What is a supercritical fluid?

Supercritical Phase Diagram

We’re all familiar with the three states of matter – Liquid, solid and gas.                                 

Let’s look at water.

  • Between 32 and 212 degrees F, water is a liquid.
  • Below 32 degrees F, water freezes and becomes a solid.
  • Above 212 degrees F, water becomes steam and is a gas.
  • If we raise the temperature of water to 705 degrees F and raise the pressure to 3191 PSI, it goes supercritical.

Carbon dioxide is the gas most often used to create supercritical fluid.

Carbon dioxide is:

  • safe and environmentally friendly
  • recyclable
  • inexpensive
  • readily available

Importantly – by using existing CO2, there is no increase in greenhouse gases

Supercritical Phase Diagram
Supercritical Technology

The conditions for supercritical carbon dioxide are very mild. CO2 becomes supercritical around 1073 PSI and 90 degrees F (31 degrees C and 74 bar.) That’s less than body temperature!

So, what is supercritical fluid

It’s not a gas, it’s not a liquid, but it has the properties and advantages of both. It has the density to dissolve but behaves like a gas. It is permeable, has high diffusivity, low viscosity, no surface tension, and it leaves no residue.

Are supercritical fluids only a laboratory phenomenon? 

No! For example, supercritical water can be found on the ocean floor around sub-marine volcanoes. At a depth of three kilometers, pressure is over three hundred atmospheres. The water is super-heated to over 375 degrees F. In areas where tectonic plates interface or where sub-marine volcanoes exist, the water in that vicinity may be supercritical.